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tfagan
Posted: Sat Sep 27, 2003 7:50 am
Guest
Will alkaline cause AL to corrode. If so why do they keep selling part
washers and recommend alkaline cleaners, I know it's primarily because of
the soils to be removed be if there is a chance that it will cause corrosion
and most a/c part are made of it why take the chance. What would be a safe
ph level, since most are mixed with water and we know water will evaporate
in these heated part cleaners that do not recommend doing a ph check prior
to putting parts in them. Is there a list of what type of cleaner should be
used with what metal because I don't think the label safe for all metals
really is correct, there to many metals that react differently to different
chemicals for that to apply to all metals

Thanks
Uncle Al
Posted: Sat Sep 27, 2003 9:50 am
Guest
tfagan wrote:
Quote:

Will alkaline cause AL to corrode. If so why do they keep selling part
washers and recommend alkaline cleaners, I know it's primarily because of
the soils to be removed be if there is a chance that it will cause corrosion
and most a/c part are made of it why take the chance. What would be a safe
ph level, since most are mixed with water and we know water will evaporate
in these heated part cleaners that do not recommend doing a ph check prior
to putting parts in them. Is there a list of what type of cleaner should be
used with what metal because I don't think the label safe for all metals
really is correct, there to many metals that react differently to different
chemicals for that to apply to all metals

Aluminum is amphoteric. It dissolves in either acid or base, e.g.,

2Al + 2NaOH + 6H2O --> 2NaAl(OH)4 + 3H2

Anything that breaches the protective oxide coating will attack
aluminum like a buzzsaw.

Alkaline cleaners are good at removing animal fats and oils via
saponification. They are also good at corroding and then dissolving
aluminum. Alkaline pitting is especially nasty. Attack upon the
metal depends on the alloy, anodization, and anti-corrosion additives
in the cleaner. I would not use aluminum in an alkaline bath unless I
did an accelerated ageing test. Remember to add a deep scratch to
part of the test specimen immediately before immersion

If you are hanging aluminum baskets from steel hooks, worry about
galvanic corrosion too. The expensive aluminum will protect the cheap
steel.

--
Uncle Al
http://www.mazepath.com/uncleal/
(Toxic URL! Unsafe for children and most mammals)
"Quis custodiet ipsos custodes?" The Net!
tfagan
Posted: Sat Sep 27, 2003 3:11 pm
Guest
Thanks for the reply could you recommend a ph limit, I was thinking around
the 10.4 range. The reason I ask is I keep telling them to look for another
cleaner and keep getting this is the only approved cleaner. I try to tell
them that alkaline cleaners can harm the AL and especially at increased
temperatures that are required for the cleaner.


"Uncle Al" <UncleAl0@hate.spam.net> wrote in message
news:3F75B1AC.333928F5@hate.spam.net...
Quote:
tfagan wrote:

Will alkaline cause AL to corrode. If so why do they keep selling part
washers and recommend alkaline cleaners, I know it's primarily because
of
the soils to be removed be if there is a chance that it will cause
corrosion
and most a/c part are made of it why take the chance. What would be a
safe
ph level, since most are mixed with water and we know water will
evaporate
in these heated part cleaners that do not recommend doing a ph check
prior
to putting parts in them. Is there a list of what type of cleaner
should be
used with what metal because I don't think the label safe for all metals
really is correct, there to many metals that react differently to
different
chemicals for that to apply to all metals

Aluminum is amphoteric. It dissolves in either acid or base, e.g.,

2Al + 2NaOH + 6H2O --> 2NaAl(OH)4 + 3H2

Anything that breaches the protective oxide coating will attack
aluminum like a buzzsaw.

Alkaline cleaners are good at removing animal fats and oils via
saponification. They are also good at corroding and then dissolving
aluminum. Alkaline pitting is especially nasty. Attack upon the
metal depends on the alloy, anodization, and anti-corrosion additives
in the cleaner. I would not use aluminum in an alkaline bath unless I
did an accelerated ageing test. Remember to add a deep scratch to
part of the test specimen immediately before immersion

If you are hanging aluminum baskets from steel hooks, worry about
galvanic corrosion too. The expensive aluminum will protect the cheap
steel.

--
Uncle Al
http://www.mazepath.com/uncleal/
(Toxic URL! Unsafe for children and most mammals)
"Quis custodiet ipsos custodes?" The Net!
Uncle Al
Posted: Sat Sep 27, 2003 4:45 pm
Guest
tfagan wrote:
Quote:

Thanks for the reply could you recommend a ph limit, I was thinking around
the 10.4 range. The reason I ask is I keep telling them to look for another
cleaner and keep getting this is the only approved cleaner. I try to tell
them that alkaline cleaners can harm the AL and especially at increased
temperatures that are required for the cleaner.

The only way to know for real is to test it for real. The higher the
temp and the higher the pH the more aggressive the corrosion.
However, a high pH cleaner may have a better corrosion inhibition
package than a lower pH but still alkaline cleaner. Remember to put a
deep scratch into your test blank immediately before immersion. You
want to know what happens in the dirty real world of modest
mentalities on the production floor.

You must test your actual basket. Alumnum foil is a different alloy
with different mechanical stress and heat treat histories.

You might google and patent search anti-corrosion packages for
automobile antifreeze that goes into aluminum engine block and
radiator engines. It would be a shame to write off a 50 gallon vat of
premium cleaner for want of a dollar's worth of additives.

--
Uncle Al
http://www.mazepath.com/uncleal/
(Toxic URL! Unsafe for children and most mammals)
"Quis custodiet ipsos custodes?" The Net!


Quote:
"Uncle Al" <UncleAl0@hate.spam.net> wrote in message
news:3F75B1AC.333928F5@hate.spam.net...
tfagan wrote:

Will alkaline cause AL to corrode. If so why do they keep selling part
washers and recommend alkaline cleaners, I know it's primarily because
of
the soils to be removed be if there is a chance that it will cause
corrosion
and most a/c part are made of it why take the chance. What would be a
safe
ph level, since most are mixed with water and we know water will
evaporate
in these heated part cleaners that do not recommend doing a ph check
prior
to putting parts in them. Is there a list of what type of cleaner
should be
used with what metal because I don't think the label safe for all metals
really is correct, there to many metals that react differently to
different
chemicals for that to apply to all metals

Aluminum is amphoteric. It dissolves in either acid or base, e.g.,

2Al + 2NaOH + 6H2O --> 2NaAl(OH)4 + 3H2

Anything that breaches the protective oxide coating will attack
aluminum like a buzzsaw.

Alkaline cleaners are good at removing animal fats and oils via
saponification. They are also good at corroding and then dissolving
aluminum. Alkaline pitting is especially nasty. Attack upon the
metal depends on the alloy, anodization, and anti-corrosion additives
in the cleaner. I would not use aluminum in an alkaline bath unless I
did an accelerated ageing test. Remember to add a deep scratch to
part of the test specimen immediately before immersion

If you are hanging aluminum baskets from steel hooks, worry about
galvanic corrosion too. The expensive aluminum will protect the cheap
steel.

--
Uncle Al
Gregg
Posted: Sat Sep 27, 2003 8:13 pm
Guest
When I use to work in the porcelain enamel industry, We developed aluminum
enamels which typically contained sodium or potassium silicate as a mill
addition.
If you were not diligent in cleaning the equipment (spray guns etc.)
immediately after use it was a real mess to clean up. As a last resort we
used boiling sodium hydroxide to remove the hardened water glass. A fairly
inexperienced technician was trying to clean a $1,500.00 Binks spray gun
which had an anodized aluminum body -
he placed it in boiling NaOH and ----- I found a pot full of steel spray gun
parts (needle, valves, springs and bushings) and no trace of the body. I
tracked down who put the pot on to boil and the technician was pissed - WHO
STOLE MY SPRAY GUN BODY AFTER I WENT TO THE TROUBLE OF CLEANING IT!!!
- - it took a while to explain to him that he just dissolved an expensive
spray gun.
When in doubt of procedures - fall back on training - or lack there of.
Gregg
"Uncle Al" <UncleAl0@hate.spam.net> wrote in message
news:3F7612F4.6C8479D3@hate.spam.net...
Quote:
tfagan wrote:

Thanks for the reply could you recommend a ph limit, I was thinking
around
the 10.4 range. The reason I ask is I keep telling them to look for
another
cleaner and keep getting this is the only approved cleaner. I try to
tell
them that alkaline cleaners can harm the AL and especially at increased
temperatures that are required for the cleaner.

The only way to know for real is to test it for real. The higher the
temp and the higher the pH the more aggressive the corrosion.
However, a high pH cleaner may have a better corrosion inhibition
package than a lower pH but still alkaline cleaner. Remember to put a
deep scratch into your test blank immediately before immersion. You
want to know what happens in the dirty real world of modest
mentalities on the production floor.

You must test your actual basket. Alumnum foil is a different alloy
with different mechanical stress and heat treat histories.

You might google and patent search anti-corrosion packages for
automobile antifreeze that goes into aluminum engine block and
radiator engines. It would be a shame to write off a 50 gallon vat of
premium cleaner for want of a dollar's worth of additives.

--
Uncle Al
http://www.mazepath.com/uncleal/
(Toxic URL! Unsafe for children and most mammals)
"Quis custodiet ipsos custodes?" The Net!


"Uncle Al" <UncleAl0@hate.spam.net> wrote in message
news:3F75B1AC.333928F5@hate.spam.net...
tfagan wrote:

Will alkaline cause AL to corrode. If so why do they keep selling
part
washers and recommend alkaline cleaners, I know it's primarily
because
of
the soils to be removed be if there is a chance that it will cause
corrosion
and most a/c part are made of it why take the chance. What would be
a
safe
ph level, since most are mixed with water and we know water will
evaporate
in these heated part cleaners that do not recommend doing a ph check
prior
to putting parts in them. Is there a list of what type of cleaner
should be
used with what metal because I don't think the label safe for all
metals
really is correct, there to many metals that react differently to
different
chemicals for that to apply to all metals

Aluminum is amphoteric. It dissolves in either acid or base, e.g.,

2Al + 2NaOH + 6H2O --> 2NaAl(OH)4 + 3H2

Anything that breaches the protective oxide coating will attack
aluminum like a buzzsaw.

Alkaline cleaners are good at removing animal fats and oils via
saponification. They are also good at corroding and then dissolving
aluminum. Alkaline pitting is especially nasty. Attack upon the
metal depends on the alloy, anodization, and anti-corrosion additives
in the cleaner. I would not use aluminum in an alkaline bath unless I
did an accelerated ageing test. Remember to add a deep scratch to
part of the test specimen immediately before immersion

If you are hanging aluminum baskets from steel hooks, worry about
galvanic corrosion too. The expensive aluminum will protect the cheap
steel.

--
Uncle Al
 
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