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Science Forum Index » Chemistry Forum » Why can't we manufacture oil?...
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| Pietro... |
Posted: Thu Jun 19, 2008 1:33 pm |
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Guest
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I know nothing about chemistry. This question just occurred to me and
I thought you dudes might have the answer.
I'm just wondering if oil (as in the stuff that is heading for $200 a
barrel) can be manufactured in a lab/factory? It's just hydrogen,
carbon and a few other cheap and common elements right?
I assume the reason it's not is that the process required to make the
bonds/molecules is prohibitively expensive (lots of electricity?), but
- out of interest - it is possible right? And (speculatively), how
expensive would crude oil have to become to make mass production of
artificial oil viable? Are we talking about orders of magnitude or
what?
Thanks. |
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| Mark Thorson... |
Posted: Thu Jun 19, 2008 7:10 pm |
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Guest
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Pietro wrote:
Quote:
I know nothing about chemistry. This question just occurred to me and
I thought you dudes might have the answer.
I'm just wondering if oil (as in the stuff that is heading for $200 a
barrel) can be manufactured in a lab/factory? It's just hydrogen,
carbon and a few other cheap and common elements right?
Plus energy. Where do you get the energy?
Quote: I assume the reason it's not is that the process required to make the
bonds/molecules is prohibitively expensive (lots of electricity?), but
- out of interest - it is possible right? And (speculatively), how
expensive would crude oil have to become to make mass production of
artificial oil viable? Are we talking about orders of magnitude or
what?
Do a Google search on "nuclear hydrogen".
It has no carbon footprint, and it can be
made available in unlimited quantities
without paving one of our states with
solar cells.
You can start here:
http://www.ne.doe.gov/nhi/nenhi.html |
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| Craig... |
Posted: Thu Jun 19, 2008 7:12 pm |
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Guest
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On Jun 19, 4:33 pm, Pietro <pietro... at (no spam) gmail.com> wrote:
Quote: I know nothing about chemistry. This question just occurred to me and
I thought you dudes might have the answer.
I'm just wondering if oil (as in the stuff that is heading for $200 a
barrel) can be manufactured in a lab/factory? It's just hydrogen,
carbon and a few other cheap and common elements right?
I assume the reason it's not is that the process required to make the
bonds/molecules is prohibitively expensive (lots of electricity?), but
- out of interest - it is possible right? And (speculatively), how
expensive would crude oil have to become to make mass production of
artificial oil viable? Are we talking about orders of magnitude or
what?
Thanks.
Hello Pietro,
In principle, it is possible. As you suspect, it is not currently
viable.
The basic problem boils down to energy. What makes oil so great is
that, by reacting it with oxygen (which is available for free from the
air), we can release lots of energy. So, theoretically, we could take
the stuff that oil turns into when it burns, and transform it back
into oil. However, this would cost energy. Where does this energy
come from? All of the "alternative energy" technologies out there
have different ways of answering that last question.
The important part is that we need to get energy from *somewhere*. We
can't just pull it out of thin air for free. Oil gives us energy by
reacting with oxygen. Solar energy comes from sunlight. Nuclear
energy comes from certain nuclear reactions (uranium fission, etc.).
Windmills obtain energy from the wind. And so on.
We consume oil because it comes out of the ground in a form that's
very easy to use. For example, solar energy has the problem that we
need a way to store it, so we can use it even when the sun isn't
shining. We could transform some other energy (e.g. solar) into oil,
if we really wanted, but we would still need to get that energy from
someplace, somehow. There's also a further complication than any time
you convert energy, you always lose some to inefficiency. So, for
synthetic oil to be viable, some *other* kind of energy would have to
be substantially cheaper than simply shoving a pipe into the ground
and burning what gets pumped up. (I exaggerate the simplicity of
using oil, but you get the idea.)
As an example, one process that makes synthetic oil is the Fischer-
Tropsch process. This can turn certain chemicals (hydrogen and carbon
monoxide) into "oil", under the right conditions. The feedstock can
be easily obtained from other fossil fuels, like coal or natural gas.
You can see how this might be attractive, if you have lots of coal
lying around, but not so much oil.
As a matter of historical fact, the Fischer-Tropsch (FT) process has
only been used three times since it was invented about a century ago.
The first time was in Nazi Germany during World War II. Germany was
blockaded by its enemies, and could not obtain Arabian oil to power
their tanks/planes/etc.. So, they used FT to make what they could not
otherwise get. The second time was in South Africa. South Africa was
embargoed because of its apartheid policies, so for similar reasons,
they had to make what they could not trade to get. The third time is
currently (as far as I know) in Southeast Asia. Indonesia and
Malaysia have large reserves of natural gas, but no oil. They want to
sell their natural gas, like the Arabians sell their oil, but it's a
lot more awkward to transport a gas than a liquid. So, they have
adapted FT to turn natural gas into a liquid, and they sell that.
Remember, it still costs them energy to transform the natural gas, but
it happens to work out that oil is so much more valuable, and natural
gas is so cheap for them to get (and so hard to sell), that it ends up
being worthwhile.
What's my point? The Fischer-Tropsch process exists and can crank out
as much synthetic oil as you care to make. We've known how to do it
for a very long time. However, it has only been worth using in a few
isolated situations.
I don't have enough specific knowledge to tell you exactly what would
be needed for some way of getting synthetic oil to take off (e.g. oil
at $X/barrel). It depends not only on the cost of oil, but also on
the cost of making synthetic oil, or whatever other form of stored
energy (e.g. hydrogen, etc.). Again, something else would have to be
*so* much cheaper than oil, to make it worthwhile.
I hope that answers your question.
- Craig |
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Posted: Thu Jun 19, 2008 8:19 pm |
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Guest
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On Jun 19, 4:33 pm, Pietro <pietro... at (no spam) gmail.com> wrote:
Quote: I know nothing about chemistry. This question just occurred to me and
I thought you dudes might have the answer.
I'm just wondering if oil (as in the stuff that is heading for $200 a
barrel) can be manufactured in a lab/factory? It's just hydrogen,
carbon and a few other cheap and common elements right?
Yep. Pretty much just bottled energy.
Quote: I assume the reason it's not is that the process required to make the
bonds/molecules is prohibitively expensive (lots of electricity?), but
- out of interest - it is possible right? And (speculatively), how
expensive would crude oil have to become to make mass production of
artificial oil viable? Are we talking about orders of magnitude or
what?
As Craig said, Fischer-Tropsch. (synthesis of oils from hydrogen and
carbon monoxide) Hydrogen can be made from electrolysis of water
(LOTS of electricity - we're talking gigawatts here, to produce enough
oil to rival a refinery.) And carbon monoxide can be made from
reacting concentrated carbon dioxide with more hydrogen.
The Fischer-Tropsch reactors are not cheap (high-pressure vessels
usually aren't cheap), the reaction is messy (lots of thick waxes
form, plug up the catalyst, catalyst has to be burned off to clean it,
etc.) Oh, and did I mention it's a high-pressure reaction? Any
mistakes and... kaBOOM!
It probably becomes economical somewhere between $5 and $10 a gallon
of gasoline. Some brave businessmen have to raise several billion
dollars to build the chemical plant (the economics get better the
bigger the plant).
Other than that, it's pretty straightforward, been studied to death
for at least the last 60 years, etc. If our government can invade
Iraq at $2 trillion, our government can build synthetic Fischer-
Tropsch plants.
No problem.
Michael |
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Posted: Fri Jun 20, 2008 6:26 am |
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Guest
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On Jun 19, 4:33 pm, Pietro <pietro... at (no spam) gmail.com> wrote:
Quote: I know nothing about chemistry. This question just occurred to me and
I thought you dudes might have the answer.
I'm just wondering if oil (as in the stuff that is heading for $200 a
barrel) can be manufactured in a lab/factory? It's just hydrogen,
carbon and a few other cheap and common elements right?
On that note, pretty much any fruit tree can convert carbon dioxide
and water into a sugar-filled fruit, which can then be fermented by
yeast into a beer-like substance containing 5-10% ethanol, then
distilled to concentrate the ethanol for burning in the gas tank. The
only equipment needed in this case are the fermentation vessel and the
distillation column.
It is left as an exercise to the reader to justify this alternative
use of food, when millions around the world go without enough food to
eat each day. It may be better to make the ethanol from cafeteria
food scraps.
http://running_on_alcohol.tripod.com/id1.html
"What materials are required to make ethanol once I have a still set
up? First, you need a good source of feedstock. By feedstock, I mean
a good source of sugar or starch (carbohydrates) which can be
fermented in the same process as which you make beer or wine. You
aren't going to drink it, so it can be somewhat contaminated: For
example, we once made a batch from a weeks' garbage from a low-
security prison (one of our CAPFA founders worked there), so he
separated it out for us. It was mostly lumpy mashed potatoes and stale
bread, and we had to fight off the flies while we ran mixed it with
water and dumped it into a larger fermentation tank. Then we covered
it with window screen to keep the flies away."
Michael |
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| Dirk Bruere at NeoPax... |
Posted: Fri Jun 20, 2008 9:40 am |
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Guest
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mrdarrett at (no spam) gmail.com wrote:
Quote: On Jun 19, 4:33 pm, Pietro <pietro... at (no spam) gmail.com> wrote:
I know nothing about chemistry. This question just occurred to me and
I thought you dudes might have the answer.
I'm just wondering if oil (as in the stuff that is heading for $200 a
barrel) can be manufactured in a lab/factory? It's just hydrogen,
carbon and a few other cheap and common elements right?
Yep. Pretty much just bottled energy.
I assume the reason it's not is that the process required to make the
bonds/molecules is prohibitively expensive (lots of electricity?), but
- out of interest - it is possible right? And (speculatively), how
expensive would crude oil have to become to make mass production of
artificial oil viable? Are we talking about orders of magnitude or
what?
As Craig said, Fischer-Tropsch. (synthesis of oils from hydrogen and
carbon monoxide) Hydrogen can be made from electrolysis of water
(LOTS of electricity - we're talking gigawatts here, to produce enough
oil to rival a refinery.) And carbon monoxide can be made from
reacting concentrated carbon dioxide with more hydrogen.
The Fischer-Tropsch reactors are not cheap (high-pressure vessels
usually aren't cheap), the reaction is messy (lots of thick waxes
form, plug up the catalyst, catalyst has to be burned off to clean it,
etc.) Oh, and did I mention it's a high-pressure reaction? Any
mistakes and... kaBOOM!
It probably becomes economical somewhere between $5 and $10 a gallon
of gasoline. Some brave businessmen have to raise several billion
dollars to build the chemical plant (the economics get better the
bigger the plant).
Other than that, it's pretty straightforward, been studied to death
for at least the last 60 years, etc. If our government can invade
Iraq at $2 trillion, our government can build synthetic Fischer-
Tropsch plants.
http://timesofindia.indiatimes.com/articleshow/1758412.cms
"But a new prospect is now on the horizon: the conversion of coal to
oil. Last week, finance minister P Chidambaram disclosed that South
African company Sasol is considering investing $1 billion, rising
ultimately to $6 billion, for a project to convert Indian coal into
petroleum products.
....
Among other things, it's worried that the price of oil might suddenly
fall in the future for unanticipated reasons (like new technology). So,
it has reportedly asked the government guarantee to buy its output at
$45/barrel if the world price falls below that level."
So in India coal to oil becomes competitive at $45 per barrel.
I don't think we will be seeing that price again.
--
Dirk
http://www.transcendence.me.uk/ - Transcendence UK
Remote Viewing classes in London |
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| Marvin... |
Posted: Fri Jun 20, 2008 10:31 am |
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Guest
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We have to get the elements and energy from somewhere. But
it is possible. Gasoline and other oil products have been
made from coal going back to WW II. But it hasn't been
cost-effective most of the time. It is being considered
seriously now, but in the U.S. the current administration
hasn't been supportive. They would rather just drill for
more oil in environmentally sensitive places. |
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| Fred Kasner... |
Posted: Tue Jun 24, 2008 6:14 pm |
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Guest
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Craig wrote:
Quote: On Jun 19, 4:33 pm, Pietro <pietro... at (no spam) gmail.com> wrote:
I know nothing about chemistry. This question just occurred to me and
I thought you dudes might have the answer.
I'm just wondering if oil (as in the stuff that is heading for $200 a
barrel) can be manufactured in a lab/factory? It's just hydrogen,
carbon and a few other cheap and common elements right?
I assume the reason it's not is that the process required to make the
bonds/molecules is prohibitively expensive (lots of electricity?), but
- out of interest - it is possible right? And (speculatively), how
expensive would crude oil have to become to make mass production of
artificial oil viable? Are we talking about orders of magnitude or
what?
Thanks.
Hello Pietro,
In principle, it is possible. As you suspect, it is not currently
viable.
The basic problem boils down to energy. What makes oil so great is
that, by reacting it with oxygen (which is available for free from the
air), we can release lots of energy. So, theoretically, we could take
the stuff that oil turns into when it burns, and transform it back
into oil. However, this would cost energy. Where does this energy
come from? All of the "alternative energy" technologies out there
have different ways of answering that last question.
The important part is that we need to get energy from *somewhere*. We
can't just pull it out of thin air for free. Oil gives us energy by
reacting with oxygen. Solar energy comes from sunlight. Nuclear
energy comes from certain nuclear reactions (uranium fission, etc.).
Windmills obtain energy from the wind. And so on.
We consume oil because it comes out of the ground in a form that's
very easy to use. For example, solar energy has the problem that we
need a way to store it, so we can use it even when the sun isn't
shining. We could transform some other energy (e.g. solar) into oil,
if we really wanted, but we would still need to get that energy from
someplace, somehow. There's also a further complication than any time
you convert energy, you always lose some to inefficiency. So, for
synthetic oil to be viable, some *other* kind of energy would have to
be substantially cheaper than simply shoving a pipe into the ground
and burning what gets pumped up. (I exaggerate the simplicity of
using oil, but you get the idea.)
As an example, one process that makes synthetic oil is the Fischer-
Tropsch process. This can turn certain chemicals (hydrogen and carbon
monoxide) into "oil", under the right conditions. The feedstock can
be easily obtained from other fossil fuels, like coal or natural gas.
You can see how this might be attractive, if you have lots of coal
lying around, but not so much oil.
As a matter of historical fact, the Fischer-Tropsch (FT) process has
only been used three times since it was invented about a century ago.
The first time was in Nazi Germany during World War II. Germany was
blockaded by its enemies, and could not obtain Arabian oil to power
their tanks/planes/etc.. So, they used FT to make what they could not
otherwise get. The second time was in South Africa. South Africa was
embargoed because of its apartheid policies, so for similar reasons,
they had to make what they could not trade to get. The third time is
currently (as far as I know) in Southeast Asia. Indonesia and
Malaysia have large reserves of natural gas, but no oil. They want to
sell their natural gas, like the Arabians sell their oil, but it's a
lot more awkward to transport a gas than a liquid. So, they have
adapted FT to turn natural gas into a liquid, and they sell that.
Remember, it still costs them energy to transform the natural gas, but
it happens to work out that oil is so much more valuable, and natural
gas is so cheap for them to get (and so hard to sell), that it ends up
being worthwhile.
What's my point? The Fischer-Tropsch process exists and can crank out
as much synthetic oil as you care to make. We've known how to do it
for a very long time. However, it has only been worth using in a few
isolated situations.
I don't have enough specific knowledge to tell you exactly what would
be needed for some way of getting synthetic oil to take off (e.g. oil
at $X/barrel). It depends not only on the cost of oil, but also on
the cost of making synthetic oil, or whatever other form of stored
energy (e.g. hydrogen, etc.). Again, something else would have to be
*so* much cheaper than oil, to make it worthwhile.
I hope that answers your question.
- Craig
Psssst! Don't tell all those countries buying oil from Indonesia that
they aren't really getting oil at all but natural gas and some kind of
ersatz oil made from natural gas.
FK |
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Posted: Wed Jun 25, 2008 8:05 pm |
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Guest
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On Jun 24, 4:14 pm, Fred Kasner <fkas... at (no spam) sbcglobal.net> wrote:
Quote: Craig wrote:
On Jun 19, 4:33 pm, Pietro <pietro... at (no spam) gmail.com> wrote:
I know nothing about chemistry. This question just occurred to me and
I thought you dudes might have the answer.
I'm just wondering if oil (as in the stuff that is heading for $200 a
barrel) can be manufactured in a lab/factory? It's just hydrogen,
carbon and a few other cheap and common elements right?
I assume the reason it's not is that the process required to make the
bonds/molecules is prohibitively expensive (lots of electricity?), but
- out of interest - it is possible right? And (speculatively), how
expensive would crude oil have to become to make mass production of
artificial oil viable? Are we talking about orders of magnitude or
what?
Thanks.
Hello Pietro,
In principle, it is possible. As you suspect, it is not currently
viable.
The basic problem boils down to energy. What makes oil so great is
that, by reacting it with oxygen (which is available for free from the
air), we can release lots of energy. So, theoretically, we could take
the stuff that oil turns into when it burns, and transform it back
into oil. However, this would cost energy. Where does this energy
come from? All of the "alternative energy" technologies out there
have different ways of answering that last question.
The important part is that we need to get energy from *somewhere*. We
can't just pull it out of thin air for free. Oil gives us energy by
reacting with oxygen. Solar energy comes from sunlight. Nuclear
energy comes from certain nuclear reactions (uranium fission, etc.).
Windmills obtain energy from the wind. And so on.
We consume oil because it comes out of the ground in a form that's
very easy to use. For example, solar energy has the problem that we
need a way to store it, so we can use it even when the sun isn't
shining. We could transform some other energy (e.g. solar) into oil,
if we really wanted, but we would still need to get that energy from
someplace, somehow. There's also a further complication than any time
you convert energy, you always lose some to inefficiency. So, for
synthetic oil to be viable, some *other* kind of energy would have to
be substantially cheaper than simply shoving a pipe into the ground
and burning what gets pumped up. (I exaggerate the simplicity of
using oil, but you get the idea.)
As an example, one process that makes synthetic oil is the Fischer-
Tropsch process. This can turn certain chemicals (hydrogen and carbon
monoxide) into "oil", under the right conditions. The feedstock can
be easily obtained from other fossil fuels, like coal or natural gas.
You can see how this might be attractive, if you have lots of coal
lying around, but not so much oil.
As a matter of historical fact, the Fischer-Tropsch (FT) process has
only been used three times since it was invented about a century ago.
The first time was in Nazi Germany during World War II. Germany was
blockaded by its enemies, and could not obtain Arabian oil to power
their tanks/planes/etc.. So, they used FT to make what they could not
otherwise get. The second time was in South Africa. South Africa was
embargoed because of its apartheid policies, so for similar reasons,
they had to make what they could not trade to get. The third time is
currently (as far as I know) in Southeast Asia. Indonesia and
Malaysia have large reserves of natural gas, but no oil. They want to
sell their natural gas, like the Arabians sell their oil, but it's a
lot more awkward to transport a gas than a liquid. So, they have
adapted FT to turn natural gas into a liquid, and they sell that.
Remember, it still costs them energy to transform the natural gas, but
it happens to work out that oil is so much more valuable, and natural
gas is so cheap for them to get (and so hard to sell), that it ends up
being worthwhile.
What's my point? The Fischer-Tropsch process exists and can crank out
as much synthetic oil as you care to make. We've known how to do it
for a very long time. However, it has only been worth using in a few
isolated situations.
I don't have enough specific knowledge to tell you exactly what would
be needed for some way of getting synthetic oil to take off (e.g. oil
at $X/barrel). It depends not only on the cost of oil, but also on
the cost of making synthetic oil, or whatever other form of stored
energy (e.g. hydrogen, etc.). Again, something else would have to be
*so* much cheaper than oil, to make it worthwhile.
I hope that answers your question.
- Craig
Psssst! Don't tell all those countries buying oil from Indonesia that
they aren't really getting oil at all but natural gas and some kind of
ersatz oil made from natural gas.
FK
You mean Malaysia, right? Shell in Bintulu?
MD |
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