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Science Forum Index » Electronics - Misc Forum » Lead free solder - exposed in a UK national newspaper
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| Phil Allison |
Posted: Thu Apr 03, 2008 10:58 pm |
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"Jay Tossers"
Quote: Another source of lead is CRTs, many of which are still in use.
They contain about 5 pounds of lead each for radiation protection,
quite a bit more than is contained in the solder in the PC boards.
** Silly comparison.
Glass does not break down in the environment.
So how would any of that lead get out ??
....... Phil |
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| N_Cook |
Posted: Fri Apr 04, 2008 1:56 am |
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Eeyore <rabbitsfriendsandrelations@hotmail.com> wrote in message
news:47F5671A.B8081A4C@hotmail.com...
Quote:
N_Cook wrote:
Eeyore <rabbitsfriendsandrelations@hotmail.com> wrote
N_Cook wrote:
http://www.guardian.co.uk/technology/2008/apr/03/research.engineering
Within a whisker of failure
About time too.
Never mind the reduced reliability (see the ERA study) caused by
lead-free
solder when equipment is exposed to vibration.
Before I waste time downloading an irrelevant pdf
would this be what you be referring to :
Review of Directive 2002/95/EC (RoHS) Categories 8 and 9 - Final
http://ec.europa.eu/environment/waste/pdf/era_study_final_report.pdf
Results of vibration testing lead-free solder from different researchers
....
Not sure if that's the one I had to be honest but looks interesting.
Graham
One small bit from that study
"Solder joint failure due to vibration becomes more significant as the
frequency of vibration approaches the resonant frequency of the component or
structure.
Studies by Chuang et al 29 and
Song et al 30 have sought to identify microstructural features that
influence the performance of conventional Sn-Pb solders and candidate
replacement lead-fre solders. The typical microstructure of conventional
Sn-Pb solders containing coarse pro-eutectic grains reduces the ability of
these materials to absorb energy during crack formation and hence reduces
the vibration resistance of joints made using these solders. "
I thoutht distributed irregularities in structures, suppressed crack
propogation.
Would seem NOT to be borne out for the case for premature failures of solder
joints for unsupported dropper resistors in mucic combos - ie amplifiers
contained within the same case as large speaker/s.
Failure in 2 or 3 years of routine use wheras more like 20 years for failure
in similar but older PbSn manufacture.
--
Diverse Devices, Southampton, England
electronic hints and repair briefs , schematics/manuals list on
http://home.graffiti.net/diverse:graffiti.net/ |
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| Arfa Daily |
Posted: Fri Apr 04, 2008 3:49 am |
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"Jay Ts" <UseWebsiteToReply@example.com> wrote in message
news:47f58171$0$8439$9a6e19ea@unlimited.newshosting.com...
Quote: Allodoxaphobia wrote:
Arfa Daily wrote:
At 30th tonnes, the potential environmental impact of the lead in
solder, even if you *did* dump it all in the ground, is minuscule.
And, where do these pin-heads think the lead came from, in the first
place?
It came from deep within the ground, in the form of lead ore,
which I think is much less of a health hazard than metallic lead
decomposing in a landfill and seeping into the water supply.
In Europe, there are places where the Romans smelted lead 2000
years ago, and 8" or so below the topsoil, the dirt is still so
toxic that health officials (in Britain at least) don't allow
people to dig there, even wearing protective gear.
BTW, I'm not a pinhead, just someone who cares about my health,
that of others and a quality environment for us to all live in.
I tried lead-free solder, and gave up on it, at least for prototyping.
I was feeling a little bad about returning to traditional solder,
until the OP posted the article. Thanks - I feel vindicated. I hope
that someday there is a better alternative to lead-based solder,
but evidently it hasn't happened yet.
Jay Ts
Basically, there isn't a lead-free alternative that works the same, or even
close, but you're missing the point(s). Firstly, there isn't *quite* such a
huge amount or disposal problem as they would have you believe. Second, the
lead in solder is pretty firmly 'locked into' the alloy, such that it
doesn't readily come out of the solder into water. Yes, I know that acid
rain can have some effect on that equation, but that's nothing like as bad
as it once was. Finally, all electronic equipment in Europe at least, is now
subject to the WEEE directive, which dictates the way it is treated at end
of life, covering recycling and disposal of the remains that can't be
recycled. There is no reason at all that leaded solder could not be
recovered and recycled, in the same way as lead free solder. 80% of the
world's metallic lead production goes to automotive battery manufacture.
Lead recovery and reuse from that product at end of life, has been mandated
and successfully carried out, for years.
I think that this is the reason that most people who have to use lead-free,
get so wound up about it. As far as I am concerned, the legislation that
mandates its use, is ill-considered, not thought through, unnnecessary in
the light of the legitimate WEEE directive, and effectively replaces a
mature and reliable technology, with one that has the potential to be
directly dangerous to human life, if it ever finds its way into avionics,
medical, and military applications, which so far, have managed to secure
exemptions.
Like any sensible person, I don't want to deliberately pollute the planet
for those who come after me, but in recent years, many badly informed
decicisions on this sort of thing, have been made by departments 'jumping on
the banwagon' to justify their own existence. The whole thing isn't helped
by celebrities and ex famous politicians serving their own public eye needs
through 'green' issues. It has actually reached the point where I am now
sick to death of hearing the words "green" and "eco" and "carbon footprint"
and "geenhouse gas" and "cimate change" and "global warming" every single
time I turn on the radio or TV. So here's a new word.
Ecobollocks. Covers what a lot of this bull actually is ...
Arfa |
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| Arfa Daily |
Posted: Fri Apr 04, 2008 4:04 am |
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"exray" <radioexray@geemail.com> wrote in message
news:47f59170$0$26120$88260bb3@free.teranews.com...
Quote: stratus46@yahoo.com wrote:
You mean the fumes from the flux. You don't believe you're breathing
solder vapors, do you? In the 40+ years I've been using solder, I
doubt I've used 5 lbs and I do quite a bit of soldering.
GG
I've never turned on my shop spectrometer to determine if it was the flux
or solder. I just know that the new stuff doesn't smell as friendly to my
human nose.
40+ years, 5 pounds, yadda,yadda...how much 'new' solder have you used? I
suspect you're just trying to pick a fight. I'm not playing. See ya.
-ex
I don't think that he's trying to pick a fight at all ... Depending on
whether or not he's talking 'professional' use, that might be a bit of an
underestimate, but not huge. I hand solder just about every day of my
working life. I use predominantly 0.7mm solder wire, which I buy in 500g
reels. I reckon that each reel lasts me probably 3 years, so in 35 years of
professional use, I have used perhaps 6kg or 13 pounds.
The reason that lead-free solder does not smell as nice, is that it is no
longer a basic natural rosin flux that is contained within the solder.
Because of the new stuff's vastly inferior wetting qualities with most
metals used in electronics, it has to contain a far more aggressive flux to
stand any chance of forming a metallic bond. That aggressive-ness is
achieved by making the flux slightly acidic, so the fumes, if you are
breathing them, are actually gently rotting the linings of your nose and
lungs. There was always a declared H & S issue about industrial asthma with
rosin flux fumes in quantity, but I suspect that this stuff is potentially a
far greater health hazard than rosin fumes ever were. So, if you're having
to use a lot of lead-free in your day to day work, I would suggest that now
is the time to install some fume management, even if it is just an old
computer fan blowing the smoke across to someone else ... :-)
Arfa |
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| Arfa Daily |
Posted: Fri Apr 04, 2008 4:12 am |
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"James Sweet" <jamessweet@hotmail.com> wrote in message
news:HOfJj.5873$yd2.3213@trndny04...
Quote:
"William Sommerwerck" <grizzledgeezer@comcast.net> wrote in message
news:ruednS26lvW_GGjanZ2dnUVZ_oWdnZ2d@comcast.com...
As I've said before... It isn't a matter of whether electronic equipment
has
lead in it, but what happens to that equipment when it's disposed of.
It's
the latter that should be considered.
And lead isn't the only toxic substance used in electronic equipment and
the process used to manufacture it.
Is a lead-free item that fails and ends up in the landfill after 2 years
better than a lead-containing device that lasts a decade?
And is then properly recycled ?
Arfa |
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| Arfa Daily |
Posted: Fri Apr 04, 2008 4:29 am |
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"Phil Allison" <philallison@tpg.com.au> wrote in message
news:65lnbrF2g8k3jU1@mid.individual.net...
Quote:
"Jay Tossers"
Another source of lead is CRTs, many of which are still in use.
They contain about 5 pounds of lead each for radiation protection,
quite a bit more than is contained in the solder in the PC boards.
** Silly comparison.
Glass does not break down in the environment.
So how would any of that lead get out ??
...... Phil
Apparently, in America, they crushed the glass to powder or some such to try
to prove this. I'm sure that someone from that side of the pond, knows the
details. The lead which is contained in the faceplate glass to minimise x
radiation to acceptable levels, is actually not metallic lead, but lead
oxide, and is very firmly locked into the molecular structure of the glass,
so wouldn't readily leach anyway. 5 pounds of lead is probably a bit on the
enthusiastic side on average. 'Big' tubes may contain this amount, or even a
little more, but average sized ones, and computer monitors, would probably
be around half or a little more, than that figure. LCD displays, of course,
do not require this radiation protection.
Arfa |
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| Robert Baer |
Posted: Fri Apr 04, 2008 4:52 am |
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TheM wrote:
Quote: "Eeyore" <rabbitsfriendsandrelations@hotmail.com> wrote in message news:47F4B8A8.ADD69B04@hotmail.com...
N_Cook wrote:
http://www.guardian.co.uk/technology/2008/apr/03/research.engineering
Within a whisker of failure
About time too.
Never mind the reduced reliability (see the ERA study) caused by lead-free
solder when equipment is exposed to vibration.
Graham
Its good for the way economy works nowadays. Buy, buy, buy the crap
that dies or obsoletes every 2-3 years.
Mark
Absolutely; we are in the replace crap with crap "economy". |
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| William Sommerwerck |
Posted: Fri Apr 04, 2008 6:57 am |
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Guest
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Quote: Is a lead-free item that fails and ends up in the landfill
after 2 years better than a lead-containing device that
lasts a decade?
And is then properly recycled?
Recycling is the issue. The only current economical way to do it is to ship
the equipment to third-world countries where poverty-stricken can dismantle
it. |
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| William Sommerwerck |
Posted: Fri Apr 04, 2008 7:02 am |
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Guest
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Quote: Like any sensible person, I don't want to deliberately pollute
the planet for those who come after me, but in recent years,
many badly informed decicisions on this sort of thing, have
been made by departments "jumping on the banwagon" to
justify their own existence.
Instead of banning polluting substances, we should be regulating the
pollution they create.
In other words, it doesn't matter how much of a harmful substance you use in
manufacturing a product, but how much of it gets into the environment. It's
the latter we should be worried about, not the former. |
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| Jay Ts |
Posted: Fri Apr 04, 2008 7:29 am |
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Guest
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Phil Allison wrote:
Quote: Jay Ts wrote:
Another source of lead is CRTs, many of which are still in use. They
contain about 5 pounds of lead each for radiation protection, quite a
bit more than is contained in the solder in the PC boards.
** Silly comparison.
Glass does not break down in the environment.
So how would any of that lead get out ??
...... Phil
My apologies, it seems I had been misinformed on that
and trusted someone who thought he understood the
situation, but didn't.
Jay Ts
--
To contact me, use this web page:
http://www.jayts.com/contact.php |
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| Jay Ts |
Posted: Fri Apr 04, 2008 7:38 am |
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William Sommerwerck wrote:
Quote: Is a lead-free item that fails and ends up in the landfill after 2
years better than a lead-containing device that lasts a decade?
And is then properly recycled?
Recycling is the issue. The only current economical way to do it is to
ship the equipment to third-world countries where poverty-stricken can
dismantle it.
I've read "news" stories on that, that said that in some (many?)
cases, they just take the money and dump the equipment in
their own landfills, so the materials are never recycled.
I don't know how true that is (if at all) but it brings up
the issue of verifying that recycling is actually done, and
done _properly_. Things that are simple in theory can get
really complicated in actual practice, so it's hard to say
whether we're better off (not just right now, but long term)
dealing with the recycling issue or just doing away with
lead and being left with the tin whiskers.
Again, I hope in the future there will be solutions that
aren't actually just compromises.
Jay Ts
--
To contact me, use this web page:
http://www.jayts.com/contact.php |
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| N_Cook |
Posted: Fri Apr 04, 2008 8:13 am |
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Guest
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William Sommerwerck <grizzledgeezer@comcast.net> wrote in message
news:V-GdnbYGe_UbimvanZ2dnUVZ_tKinZ2d@comcast.com...
Quote: Is a lead-free item that fails and ends up in the landfill
after 2 years better than a lead-containing device that
lasts a decade?
And is then properly recycled?
Recycling is the issue. The only current economical way to do it is to
ship
the equipment to third-world countries where poverty-stricken can
dismantle
it.
"recycling" as pictured here
http://www.sophiegerrard.com/
and from a now corrupted file
http://www.plusnone.com/wp-content/uploads/chrisjordan.jpg
--
Diverse Devices, Southampton, England
electronic hints and repair briefs , schematics/manuals list on
http://home.graffiti.net/diverse:graffiti.net/ |
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| James Beck |
Posted: Fri Apr 04, 2008 9:54 am |
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Guest
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In article <47f58171$0$8439$9a6e19ea@unlimited.newshosting.com>,
UseWebsiteToReply@example.com says...
Quote: Allodoxaphobia wrote:
Arfa Daily wrote:
At 30th tonnes, the potential environmental impact of the lead in
solder, even if you *did* dump it all in the ground, is minuscule.
And, where do these pin-heads think the lead came from, in the first
place?
It came from deep within the ground, in the form of lead ore,
which I think is much less of a health hazard than metallic lead
decomposing in a landfill and seeping into the water supply.
Mettalic lead has been shown to have very little impact on the
environment. Especially after it has built up an oxide layer.
Quote:
In Europe, there are places where the Romans smelted lead 2000
years ago, and 8" or so below the topsoil, the dirt is still so
toxic that health officials (in Britain at least) don't allow
people to dig there, even wearing protective gear.
Ah, but we aren't talking about running a smelting operation, are we?
Quote:
BTW, I'm not a pinhead, just someone who cares about my health,
that of others and a quality environment for us to all live in.
I don't know.
Comparing burying metallic lead VS a smelting operation, that borders on
pinheadiness.
Quote:
I tried lead-free solder, and gave up on it, at least for prototyping.
I was feeling a little bad about returning to traditional solder,
until the OP posted the article. Thanks - I feel vindicated. I hope
that someday there is a better alternative to lead-based solder,
but evidently it hasn't happened yet.
Jay Ts
Until they come up with better alternatives, I'll stick with good old
lead/tin. When I left my last job, I had a full physical including a
lead test, and even though I had been "exposed" to lead solder almost
daily for 13 years, my blood lead levels were almost not measurable and
that puts me below the national average for people that don't work with
solder at all. Why would that be if lead/tin solder were so dangerous?
Jim |
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| James Beck |
Posted: Fri Apr 04, 2008 9:56 am |
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Guest
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In article <WpidnUlI36dOhWvanZ2dnUVZ_rGhnZ2d@comcast.com>,
grizzledgeezer@comcast.net says...
Quote: Like any sensible person, I don't want to deliberately pollute
the planet for those who come after me, but in recent years,
many badly informed decicisions on this sort of thing, have
been made by departments "jumping on the banwagon" to
justify their own existence.
Instead of banning polluting substances, we should be regulating the
pollution they create.
In other words, it doesn't matter how much of a harmful substance you use in
manufacturing a product, but how much of it gets into the environment. It's
the latter we should be worried about, not the former.
I think you have hit on something here. |
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| msg |
Posted: Fri Apr 04, 2008 10:40 am |
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Guest
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Arfa Daily wrote:
<snip>
Quote: It has actually reached the point where I am now
sick to death of hearing the words "green" and "eco" and "carbon footprint"
and "geenhouse gas" and "cimate change" and "global warming" every single
time I turn on the radio or TV. So here's a new word.
Ecobollocks. Covers what a lot of this bull actually is ...
Sentiment seconded.
Message sorted headers by date from my nntp provider:
Re: Lead free solder - exposed in a UK national newspaper Arfa Daily
Lead Generation Computer Systems liukaiyuan
....
I expected to see an advert for cpus soldered with 63/36 or 60/40 ;)
Michael |
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