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verdigris
Posted: Sat Mar 03, 2007 8:34 am
Guest
Pons and Fleischman used a palladium cathode in their cold fusion
experiment of 1989 (cathode immersed in heavy water,D20)and they said
that excess energy was released from the system.
Since 1989 lots of experiments have been done and some researchers
have agreed with the findings of Pons and Fleischman.
I have seen many explanations of why cold fusion can't take place
according to known physics but here is one suggestion I have as to why
it can!
Palladium metal is very resistant to fracturing.This means that
impurity atoms or ions face a high energy barrier to get into the
crystal lattice and distort the face-centred cubic arrangement,and
that it is difficult for defects to grow larger to cause fracturing.
But when an electric current flows through palladium metal (which has
hydrogen gas on its surface and inside it - palladium absorbs 900
times its own volume of hydrogen) hydrogen molecules and hydrogen ions
(which are present in the heavy water) are given the energy to distort
the metal structure and remain in situ.As time passes the number of
distortions and hence the potential energy of the palladium cathode
increases.At some critical point, the face-centred cubic arrangement
of palladium atoms is quickly restored
and the hydrogen molecules and ions are expelled from the palladium
cathode, as potential energy is released like a mini-earthquake.In a
cylindrical-shaped cathode the released energy could be focused at its
end or in the centre of the rod.In particular,
at some locations in the rod where deuterium molecules are located,
the focused energy could be sufficient to cause helium 4 to form.The
formation of helium inside the cathode would explain why nuclear
products have rarely been detected in the heavy water in experiments
of this type.
jwill@BasicISP.net
Posted: Tue Mar 06, 2007 3:48 am
Guest
Hi.

You are merely reasoning by analogy. If you would think about what
you
are writing, you might realize a fatal flaw: There is no such thing
as
"concentrated energy" among molecules. The energy is released as
photons, and you must use quantum mechanics, not gigantic
earthquakes, as the basis of inference. All the molecular bonds
involved
are mediated by virtual photons which define the electronic levels
and interactions.

All energy exchange at the levels you describe is mediated by photons,
and the energy of a photon in a chemical bond is about 15 orders of
magnitude
too low to allow it to participate in nuclear reactions.

If a deuterium atom was located somewhere, its electronic shell would
define
the maximum energy transferable to the nucleus. Nothing more.

Chemical changes occur at time scales GLACIALLY SLOW (if you want
analogies) when compared with strong-force changes in the nucleus.
Nuclei simply move when affected by the energies you describe; their
shape
doesn't change at all -- not to mention any differential change of the
neutrons
and proton(s) involved.

The cold fusion idea is just a mistake -- maybe a natural one -- which
has been maintained, I think, only by pride and an unwilingness to
learn from
experience.

verdigris wrote:
Quote:
Pons and Fleischman used a palladium cathode in their cold fusion
experiment of 1989 (cathode immersed in heavy water,D20)and they said
that excess energy was released from the system.
Since 1989 lots of experiments have been done and some researchers
have agreed with the findings of Pons and Fleischman.
I have seen many explanations of why cold fusion can't take place
according to known physics but here is one suggestion I have as to why
it can!
Palladium metal is very resistant to fracturing.This means that
impurity atoms or ions face a high energy barrier to get into the
crystal lattice and distort the face-centred cubic arrangement,and
that it is difficult for defects to grow larger to cause fracturing.
But when an electric current flows through palladium metal (which has
hydrogen gas on its surface and inside it - palladium absorbs 900
times its own volume of hydrogen) hydrogen molecules and hydrogen ions
(which are present in the heavy water) are given the energy to distort
the metal structure and remain in situ.As time passes the number of
distortions and hence the potential energy of the palladium cathode
increases.At some critical point, the face-centred cubic arrangement
of palladium atoms is quickly restored
and the hydrogen molecules and ions are expelled from the palladium
cathode, as potential energy is released like a mini-earthquake.In a
cylindrical-shaped cathode the released energy could be focused at its
end or in the centre of the rod.In particular,
at some locations in the rod where deuterium molecules are located,
the focused energy could be sufficient to cause helium 4 to form.The
formation of helium inside the cathode would explain why nuclear
products have rarely been detected in the heavy water in experiments
of this type.
verdigris
Posted: Tue Mar 06, 2007 3:48 am
Guest
I thought I should add that the adsorption of hydrogen by palladium is
not well understood - 900 times the volume of palladium is adsorbed
and it isn't know if palladium hydride forms inside the material.The
hydrogen gas isn't polar like water molecules,for example,and so it's
hard to see how the gas moves so freely into the palladium since there
doesn't seem to be a cohesion-adheson effect.It's almost as though the
repulsive electric force has been weakened - something that would help
overcome the fusion energy barrier.I can only speculate that if this
is happening for some hydrogen atoms then others are aving the fusion
energy barrier raised.But this would be new physics!
verdigris
Posted: Tue Mar 06, 2007 3:48 am
Guest
After reading this link:

http://www.psc.edu/science/Wolf/Wolf.html

and seeing the hydrogen molecules in such close proximity to the
palladium atoms,I think that the palladium is giving electron density
to the hydrogen molecules and shortening their bond lengths,and that
the palladium atoms
having lost some electron density are repelling each other more
electrically,and increasing their bond lengths as more hydrogen enters
the system
(palladium is known to expand as hydrogen enters it).This would
explain why there is no back pressure stopping more hydrogen from
entering he palladium metal sample.
The pd-pd bond length would have to increase 2.5 times to accomodate
900 times the palladium's own volume of hydrogen ( 2.5 ^ 3 is
approximately 15, and before expansion each face-centred cubic pd unit
could contain a maximum of 60 hydrogen molecules - 15 x 60 = 900).
Murray Arnow
Posted: Tue Mar 06, 2007 3:49 am
Guest
Dirk Bruere at NeoPax wrote:
Quote:

Ditto for sonofusion I assume?
Although such back of envelope calculations might be rather complex,
depending upon what assumptions are made.


[Drifting the thread slightly for anecdotal reasons]
BOTE calculations have to be extremely sensitive to physical insight and
clever tricks to fit in the space allotted.

The University of Chicago used to include a handful BOTE questions as part
of their candidacy examinations. I recall one question that makes me
shudder to this day. It simply asked to calculate the height of the ocean
tides. There wasn't a single candidate who took that exam who had any idea
how to do this on the back of an envelope.
Richard Saam
Posted: Tue Mar 06, 2007 5:55 pm
Guest
Murray Arnow wrote:
Quote:
Dirk Bruere at NeoPax wrote:

Ditto for sonofusion I assume?
Although such back of envelope calculations might be rather complex,
depending upon what assumptions are made.



[Drifting the thread slightly for anecdotal reasons]
BOTE calculations have to be extremely sensitive to physical insight and
clever tricks to fit in the space allotted.

The University of Chicago used to include a handful BOTE questions as part
of their candidacy examinations. I recall one question that makes me
shudder to this day. It simply asked to calculate the height of the ocean
tides. There wasn't a single candidate who took that exam who had any idea
how to do this on the back of an envelope.


G = gravitational constant
Me = earth mass 5.97E+27 g
Mn = moon mass 7.35E+25 g
Re = earth radius 6.371315E+08 cm
Rem = distance between moon and earth 3.844E+10 cm
T = tide height
Wm = water test mass

Gravity works on a water test mass
with force from earth and moon:

G*Me*Wm/Re^2 = G*Me*Wm/(Re+T)^2 + G*Wm*Mm/(Rem)^2

cancel G and Wm

Me/Re^2 = Me/(Re+T)^2 + Mm/(Rem)^2

or

Re^2/(Re+T)^2 = 1 - (Mm/Me)*(Re/Rem)^2

Mm/Me ~ .01

Re/Rem ~ .01

Re^2/(Re+T)^2 = 1 - (.01)*(.01)^2 = 1 - 1E-6

solve ~ BOTE for T ~ 10 meters

Richard
NoEinstein
Posted: Wed Mar 07, 2007 5:11 pm
Guest
On Mar 6, 10:55 pm, Richard Saam <rds...@att.net> wrote:
Quote:
Murray Arnow wrote:
Dirk Bruere at NeoPax wrote:

Ditto for sonofusion I assume?
Although such back of envelope calculations might be rather complex,
depending upon what assumptions are made.

[Drifting the thread slightly for anecdotal reasons]
BOTE calculations have to be extremely sensitive to physical insight and
clever tricks to fit in the space allotted.

The University of Chicago used to include a handful BOTE questions as part
of their candidacy examinations. I recall one question that makes me
shudder to this day. It simply asked to calculate the height of the ocean
tides. There wasn't a single candidate who took that exam who had any idea
how to do this on the back of an envelope.

G = gravitational constant
Me = earth mass 5.97E+27 g
Mn = moon mass 7.35E+25 g
Re = earth radius 6.371315E+08 cm
Rem = distance between moon and earth 3.844E+10 cm
T = tide height
Wm = water test mass

Gravity works on a water test mass
with force from earth and moon:

G*Me*Wm/Re^2 = G*Me*Wm/(Re+T)^2 + G*Wm*Mm/(Rem)^2

cancel G and Wm

Me/Re^2 = Me/(Re+T)^2 + Mm/(Rem)^2

or

Re^2/(Re+T)^2 = 1 - (Mm/Me)*(Re/Rem)^2

Mm/Me ~ .01

Re/Rem ~ .01

Re^2/(Re+T)^2 = 1 - (.01)*(.01)^2 = 1 - 1E-6

solve ~ BOTE for T ~ 10 meters

Richard- Hide quoted text -

- Show quoted text -

Dear Guys, Understanding the problems with cold fusion shouldn't get
in the way of being open minded and hopeful. Many important things
have been discovered either by accident, or as the indirect result of
looking for something else. Magnetic containment fusion is way too
expensive. Lasers are a better initiator, but can't be equalized and
timed well enough. But I have a design for initiating (hot) fusion
with a single laser by using preconcentrated fuel pellets that are
very close to the critical pressure before the laser hits. The
accoustic shape of the pellets concentrates the laser even more-
hopefully allowing sequencial fusion of pellets. Those are stored in
a tubular magazine and protected from the neutrons. This is just a
concept! But solving energy problems should be the top priority of
science. NoEinstein

__________
Murray Arnow
Posted: Thu Mar 08, 2007 8:38 pm
Guest
Richard Saam wrote:
Quote:
Murray Arnow wrote:
Dirk Bruere at NeoPax wrote:

Ditto for sonofusion I assume?
Although such back of envelope calculations might be rather complex,
depending upon what assumptions are made.



[Drifting the thread slightly for anecdotal reasons]
BOTE calculations have to be extremely sensitive to physical insight and
clever tricks to fit in the space allotted.

The University of Chicago used to include a handful BOTE questions as part
of their candidacy examinations. I recall one question that makes me
shudder to this day. It simply asked to calculate the height of the ocean
tides. There wasn't a single candidate who took that exam who had any idea
how to do this on the back of an envelope.


G = gravitational constant
Me = earth mass 5.97E+27 g
Mn = moon mass 7.35E+25 g
Re = earth radius 6.371315E+08 cm
Rem = distance between moon and earth 3.844E+10 cm
T = tide height
Wm = water test mass

Gravity works on a water test mass
with force from earth and moon:

G*Me*Wm/Re^2 = G*Me*Wm/(Re+T)^2 + G*Wm*Mm/(Rem)^2

cancel G and Wm

Me/Re^2 = Me/(Re+T)^2 + Mm/(Rem)^2

or

Re^2/(Re+T)^2 = 1 - (Mm/Me)*(Re/Rem)^2

Mm/Me ~ .01

Re/Rem ~ .01

Re^2/(Re+T)^2 = 1 - (.01)*(.01)^2 = 1 - 1E-6

solve ~ BOTE for T ~ 10 meters


[This thread is well adrift and may be terminated by the moderators]

I was pretty sure that my comment would provoke a solution (I think you
have too many terms in your first equation).

Remember this was a candidacy examination question, and the candidate had
an oral exam following the written. The examiners were free to ask you
any question and would certainly ask about what you wrote on the exam.[i]
I see two problems with your solution:

1. Since you give no physical justification why this solution is valid,
didn't you just show that all free objects on the earth's surface levitate
30 ft in the air?

2. Unless you remember all those constants you used, then you cheated by
referencing a source. A major challenge in any BOTE calculation,
particularly the one in this examination, is estimating unknown constants.
Personally, I can remember one or maybe two accurately; the others I'd
need to figure out through some tricks. In this problem, I can only
off-the-cuff remember a few appropriate constants in mixed units which are
insufficient to derive the other needed quantities.

The purpose of the BOTE questions was to show how clever the candidate
was. Ok, I'm not that clever.

[i] In the good-old-days the U of C had a well-deserved bad-reputation for
its candidacy exams. There was a famous paper written by Platt in the AJP
(if my memory serves) that described some of the abuses. Nearly everyone
who took those exams heard or witnessed less than objective committee
behavior. I personally know of some outrages.
Richard Saam
Posted: Fri Mar 09, 2007 7:29 am
Guest
Uncle Al
Posted: Fri Mar 09, 2007 7:29 am
Guest
NoEinstein wrote:
[snip]

Quote:
But solving energy problems should be the top priority of
science. NoEinstein

Discovery is the top priority of science. Science does not solve
problems, science renders problems irrelevant. The whale oil crisis
of the mid-1800s was not solved by conservation, whale breeding, or
more efficient oil lamps. It was solved with petroleum.

Safe inexpensive abundant nuclear power is trivially obtained given

1) a civilian reactor design (doesn't have to fit within a
submarine),
2) a civilian use fuel recycle (gamma-contaminated fissiles back
into the reactor and a pure short half-life beta-emitter waste stream
- not a pure transuranic bomb stream and long half-life
alpha-contaminated waste),
3) and a gag glued into government's stupid corrupt controlling
mouth.

There is no physical problem attendant to abundant national energy.
Hunger is caused by climate, famine is caused by politics.

[ Mod. note: Please restrict followups to physics and not politics. -ik ]

--
Uncle Al
http://www.mazepath.com/uncleal/
(Toxic URL! Unsafe for children and most mammals)
http://www.mazepath.com/uncleal/lajos.htm#a2
verdigris
Posted: Fri Mar 09, 2007 7:29 am
Guest
On 6 Mar, 13:48, "verdigris" <waltercr...@aol.com> wrote:
Quote:
After reading this link:

 http://www.psc.edu/science/Wolf/Wolf.html

and seeing the hydrogen molecules in such close proximity to the
palladium atoms,I think that the palladium is giving electron density
to the hydrogen molecules and shortening their bond lengths,and that
the palladium atoms
having lost some electron density are repelling each other more
electrically,and increasing their bond lengths as more hydrogen enters
the system
(palladium is known to expand as hydrogen enters it).This would
explain why there is no back pressure stopping more hydrogen from
entering he palladium metal sample.
The pd-pd bond length would have to increase 2.5 times to accomodate
900 times the palladium's own volume of hydrogen ( 2.5 ^ 3 is
approximately 15, and before expansion each face-centred cubic pd unit
could contain a maximum of 60 hydrogen molecules - 15 x 60 = 900).


Verdigris:

PLEASE NOTE that although each face-centred cubic palladium unit COULD
contain a maximum of 60 hydrogen molecules ( with an external pressure
holding the palladium lattice together) there would not be anywhere
near as many as 60 molecules per face-centred cubic unit in the
situation mentioned above, where palladium spontaneously adsorbs 900
times its own volume of hydrogen.
verdigris
Posted: Sat Mar 10, 2007 3:11 pm
Guest
On 4 Mar, 19:06, scerir <sce...@libero.it> wrote:
Quote:
Murray Arnow:

Regardless of your explanation,
no one reproduced the P&F experiment.

See:
A.De Ninno, A. Frattolillo, A. Rizzo,
E. del Giudice, G. Preparata
"Experimental evidence of 4He production
in a cold fusion experiment"

Verdigris:

In this experiment where there were more deuterium atoms in the
palladium strip than palladium atoms, are we dealing with deuterium in
a palladium lattice or palladium in some sort of deuterium lattice?
Hydrogen has a hexagonal lattice at very low temperatures and
palladium has a face-centred cubic lattice at room temperature.
Hexagonal and face-centred cubic arrangements both pack atoms as
closely as is possible to achieve low energy structures.Are there
stresses in bonds in palladium which result from hydrogen trying to
achieve its hexagonal lattice configuration at the expense of
palladium's face-centred cubic configuration? Is this why so much heat
is evolved as hydrogen eneters palladium - hydrogen could be trying to
achieve hexagonal symmetry by cooling the palladium lattice
down.Chemical bonds of some kind must be forming in the palldium and
releasing energy as they do.
There is unexplained high energy bonding in butane:

http://en.wikipedia.org/wiki/Bond_rotation_barrier

This is a hydrogen rich compound.I wonder if hydrogen has a natural
propensity to try
and and form its hexagonal lattice.
verdigris
Posted: Sat Mar 10, 2007 3:11 pm
Guest
On 4 Mar, 19:06, scerir <sce...@libero.it> wrote:
Quote:
Murray Arnow:

Regardless of your explanation,
no one reproduced the P&F experiment.

See:
A.De Ninno, A. Frattolillo, A. Rizzo,
E. del Giudice, G. Preparata
"Experimental evidence of 4He production
in a cold fusion experiment"
RT/2002/41/FUShttp://lenr-canr.org/acrobat/DeNinnoAexperiment.pdf

Verdigris:

I read this paper and I can't help thinking that the electrode
"exploded" because oxygen adsorbed into the palladium cathode reacted
with hydrogen, in the presence of an electric current.However Helium 4
was produced, or there is some major flaw in how the amount of helium
4 was measured in this experiment, but I couldn't tell what it was.
jwill@BasicISP.net
Posted: Sun Mar 11, 2007 7:47 am
Guest
Dirk Bruere at NeoPax wrote:
Quote:

Not really.
Acceleration of ions in electric fields generated by fractures can
provide the necessary energy. IIRC there were neutron emissions detected
from (titanium?) cylinders of pressurised D2 when thermally cycled.

--
Dirk


The energy is not the issue. A button-cell battery has JOULES of
energy,
and fusion only liberates (or, requires) TINY fractions of a joule per
atom.

Impulse is the issue: No ion can be accelerated faster than a
hydrogen
ion, and the electric "fields" (read, virtual photon exchanges) can't
move
anything, even an electron, fast enough so that it does anything but
cause further movement of other ions, nuclei, or atoms.

To force fusion, one must cause NUCLEAR interactions, not atomic
interactions. No ionic movement caused by the puny forces in an
atomic lattice can even change the shape of a nucleus, let alone cause
it to be fused with another one. Nuclear (strong) forces adapt too
rapidly.

You might as well try to make a balloon burst by holding it in the
palm of your hand and slowly raising your hand. The nuclei will just
MOVE as a result of electronic interactions; there won't be any
nuclear
transmutation.

In the center of the Sun, temperatures are so high that the speed of a
hydrogen nucleus occasionally allows it to collide with another one
so rapidly that the nuclear forces can not adapt, and the nuclei can
fuse.
These speeds are far beyond any attainable in a solid, by atomic
motion.
scerir
Posted: Sun Mar 11, 2007 10:19 am
Guest
"verdigris"
Quote:
I read this paper and I can't help thinking that the electrode
"exploded" because oxygen adsorbed into the palladium cathode reacted
with hydrogen, in the presence of an electric current.However Helium 4
was produced, or there is some major flaw in how the amount of helium
4 was measured in this experiment, but I couldn't tell what it was.

I cannot help either. This experiment has been
carefully reviewed also by CEA (France).
In the Italian page below (but not in the English version)
you can find several links (pdf) about that experiment
and the reasons why it is still unpublished.
http://www.rainews24.rai.it/ran24/inchieste/19102006_rapporto41.asp

But in the last page of this presentation
http://www.iscmns.org/asti06/Violante.pdf
dr. Violante (ENEA), one of the five speakers at DOE 2004
about 'cold fusion', says:

'Heat effects are observed with D, but not with H,
under similar (or more severe) conditions.'

'Heat bursts exhibit an integrated energy at least
10 x greater than the sum of all possible CHEMICAL
reactions within a closed cell.'

'The accordance between revealed 4He and produced energy
seems to be a clear signature of a nuclear process
occurring in condensed matter.'

Regards,
s.
 
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